Uranium - Element information, properties and uses (2024)

Transcript :

Chemistry in its element: uranium

(Promo)

You're listening to Chemistry in its element brought to you by Chemistry World, the magazine of the Royal Society of Chemistry.

(End promo)

Chris Smith

For Chemistry in its element this week, can you guess what connects boat keels, armour piercing weaponry, beautiful coloured glass that you can track down with a geiger counter and more oxidation states than a chemist can shake a glass rod at. If not, here's Polly Arnold with the answer.

Polly Arnold

Uranium is certainly one of the most famous, or perhaps I should say infamous, elements. It is the heaviest naturally occurring element. It is actually more abundant in the earth's crust than silver. It is one of eight elements named in honour of celestial objects, but you might not think that uranium deserves to be named after the planet Uranus. The lustrous black powder that the chemist Klaproth isolated from the mineral pitchblende in 1789 - just eight years after Uranus was discovered - was in fact an oxide of uranium. Not until fifty two years later did Eugène Melchior Peligot reduced uranium tetrachloride with potassium, and from these harsher conditions obtained the pure silvery white metal at last. Samples of the metal tarnish rapidly in air, but if the metal is finely divided, it will burst into flames.

Uranium sits amongst the actinides, the second shell of metals to fill their f-orbitals with valence electrons, making them large and weighty.

Chemically, uranium is fascinating. Its nucleus is so full of protons and neutrons that it draws its core electron shells in close. This means relativistic effects come into play that affect the electron orbital energies. The inner core s electrons move faster, and are drawn in to the heavy nucleus, shielding it better. So the outer valence orbitals are more shielded and expanded, and can form hybrid molecular orbitals that generated arguments over the precise ordering of bonding energies in the uranyl ion until as recently as this century.

This means that a variety of orbitals can now be combined to make bonds, and from this, some very interesting compounds. In the absence of air, uranium can display a wide range of oxidation states, unlike the lanthanides just above it, and it forms many deeply coloured complexes in its lower oxidation states. The uranium tetrachloride that Peligot reduced is a beautiful grass-green colour, while the triiodide is midnight-blue. Because of this, some regard it as a 'big transition metal'. Most of these compounds are hard to make and characterise as they react so quickly with air and water, but there is still scope for big breakthroughs in this area of chemistry.

The ramifications of relativistic effects on the energies of the bonding electrons has generated much excitement for us synthetic chemists, but unfortunately many headaches for experimental and computational chemists who are trying to understand how better to deal with our nuclear waste legacy.

In the environment, uranium invariably exists as a dioxide salt called the uranyl ion, in which it is tightly sandwiched between two oxygen atoms, in its highest oxidation state. Uranyl salts are notoriously unreactive at the oxygen atoms, and about half of all known uranium compounds contain this dioxo motif. One of the most interesting facets of this area of uranium chemistry has emerged in the last couple of years: A few research groups have found ways to stabilise the singly reduced uranyl ion, a fragment which was traditionally regarded as too unstable to isolate. This ion is now beginning to show reactivity at its oxygen atoms, and may be able to teach us much about uranium's more radioactive and more reactive man-made sisters, neptunium and plutonium - these are also present in nuclear waste, but difficult to work with in greater than milligram quantities.

Outside the chemistry lab, uranium is best known for its role as a nuclear fuel. It has been at the forefront of many chemists' consciousness over recent months due to the international debate on the role that nuclear power can play in a future as a low-carbon energy source, and whether our new generations of safer and efficient power stations are human-proof.

To make the fuel that is used to power reactors to generate electricity, naturally occurring uranium, which is almost all U-238, is enriched with the isotope U-235 which is normally only present in about 0.7 %.

The leftovers, called depleted uranium, or DU, have a much-reduced U-235 content of only about 0.2 %. This is 40 % less radioactive than natural uranium, and the material that we use to make compounds from in the lab.

Because it is so dense, DU is also used in shielding, in the keels of boats and more controversially, in the noses of armour-piercing weapons. The metal has the desirable ability to self-sharpen as it pierces a target, rather than mushrooming upon impact the way conventional tungsten carbide tipped weapons do.

Critics of DU weaponry claim it can accumulate around battlefields. Because uranium is primarily an alpha-emitter, its radioactivity only really becomes a problem if it gets inside the body, where it can accumulate in the kidneys, causing damage. However, uranium is also a heavy metal, and its chemical toxicity is of greater importance - it is approximately as toxic as lead or mercury.

But uranium doesn't deserve it's image as one of the periodic table's nasties. Much of the internal heat of the earth is considered to be due to the decay of natural uranium and thorium deposits. Perhaps those looking to improve the public image of nuclear power should demand the relabelling of geothermal ground-source heat pumps as nuclear?

The reputation of this element would also be significantly better if only uranium glass was the element's most publicly known face. In the same way that lead salts are added to glass to make sparkling crystal glassware, uranyl salts give a very beautiful and translucent yellow-green colour to glass, although glassmakers have experimented to produce a wide range of gem-like colours. An archaeological dig near Naples in 1912 unearthed a small green mosaic tile dated back to 79 AD, which was reported to contain uranium, but these claims have not been verified. However in the early-19th and early 20th century it was used widely in containers and wine-glasses. If you think that you own a piece, you can check with a Geiger counter, or by looking for the characteristic green fluorescence of the uranium when held under a UV-lamp. Pieces are generally regarded as safe to drink from, but you are advised not to drill holes in them, or wear them. Fair enough.

Chris Smith

Or inadvertently eating it too, presumably. That was Edinburgh University chemist Polly Arnold explaining the softer side of the armour piercing element Uranium. Next week Andrea Sella will be introducing us to some crystals with intriguing properties.

Andrea Sella

"It's amazing stuff. You HAVE to see this." He pulled out of his pocket a sample vial containing some stunning pink crystals that glinted alluringly. "Wow!" I said - you can always impress a chemist with nice crystalline products. "It gets better." he said mysteriously. He beckoned me into a hallway. "Look" he said. As the crystals caught the light from the new fluorescent lights hanging from the ceiling, the pink colour seemed to deepen and brighten up. "Wow!" I said again. We moved the crystals back into the sunlight and the colour faded again, and moving the crystals back and forth they glowed and dimmed in magical fashion.

Chris Smith

But what did they contain? Well, the answer's Erbium and you can hear all about it in next week's Chemistry in its element. I'm Chris Smith, thank you for listening and goodbye.

(Promo)

Chemistry in its element is brought to you by the Royal Society of Chemistry and produced bythenakedscientists.com. There's more information and other episodes of Chemistry in its element on our website atchemistryworld.org/elements.

(End promo)

Uranium
    - Element information, properties and uses (2024)

FAQs

Uranium - Element information, properties and uses? ›

Uranium is also used by the military to power nuclear submarines and in nuclear weapons. Depleted uranium is uranium that has much less uranium-235 than natural uranium. It is considerably less radioactive than natural uranium. It is a dense metal that can be used as ballast for ships and counterweights for aircraft.

What are 3 things uranium is used for? ›

Uranium is now used to power commercial nuclear reactors that produce electricity and to produce isotopes used for medical, industrial, and defense purposes around the world.

Is uranium a metal or metalloid? ›

Uranium is a hard, dense, malleable, ductile, silver-white, radioactive metal. Uranium metal has very high density.

What element family is uranium in? ›

uranium (U), radioactive chemical element of the actinoid series of the periodic table, atomic number 92.

What are the properties of uranium? ›

Uranium is an actinide element, and has the highest atomic mass of any naturally occurring element. In its refined state, it is a heavy, silvery-white metal that is malleable, ductile, slightly paramagnetic, and very dense, second only to tungsten.

What is the biggest use of uranium? ›

Uranium is the most-used fuel by nuclear power plants for nuclear fission. Uranium is a common metal found in rocks all over the world. Uranium occurs in combination with small amounts of other elements.

Is uranium illegal? ›

US Nuclear Regulatory Commission regulations at 10 CFR 40.25 establish a general license for the use of depleted uranium contained in industrial products or devices for mass-volume applications. This general license allows anyone to possess or use depleted uranium for authorized purposes.

Is uranium toxic? ›

Main uranium health effects

Uranium's main target is the kidneys. Kidney damage has been seen in humans and animals after inhaling or ingesting uranium compounds. However, kidney damage has not been consistently found in soldiers who have had uranium metal fragments in their bodies for several years.

Is uranium edible? ›

Will I die if I eat uranium? Consuming 25 milligrams will immediately wreak havoc on the kidneys. Ingesting more than 50 milligrams can result in kidney failure and even cause death.

Does uranium actually glow? ›

Perhaps the most reliable way to identify the presence of uranium in the glass is to expose it in the dark to a source of ultraviolet light (e.g., a black light). If the glass glows a rich green color, it contains uranium.

What does uranium smell like? ›

Uranium is a metal that has no smell or taste. Uranium is naturally present in bedrock in many places throughout CT. When a drinking water well is drilled into bedrock containing uranium, the uranium can get into the well water.

Is uranium glass safe? ›

In fact, a report published by the US Nuclear Regulatory Commission in 2001 stated that uranium glass is considered to be safer than household electronics. Despite this, it is recommended that you avoid eating or drinking out of uranium glass objects, as you can end up ingesting small fragments of radioactive material.

What is magical about uranium? ›

Uranium spits energy unlike any other rock. Its energy transforms DNA and shapes the very nature of what it means to be human. You are who you are because of Uranium. Uranium is a changeling.

Is uranium flammable? ›

* Uranium powder is FLAMMABLE and a FIRE HAZARD. * Uranium is a radioactive isotope and is regulated by the Nuclear Regulatory Commission (NRC).

What can uranium bond with? ›

Uranium metal reacts with almost all nonmetallic elements and their compounds, with reactivity increasing with temperature. Hydrochloric and nitric acids dissolve uranium, but non-oxidizing acids other than hydrochloric acid attack the element very slowly. When finely divided, it can react with cold water.

What can spent uranium be used for? ›

Depleted uranium is used for tank armor, armor-piercing bullets, and as weights to help balance aircrafts. Depleted uranium is both a toxic chemical and radiation health hazard when inside the body.

What are the 3 ways to mine uranium? ›

Uranium Recovery (Extraction) Methods
  • Conventional Uranium Mills.
  • In Situ Recovery Facilities.
  • Heap Leach and Ion-Exchange Facilities.
  • Comparison of Conventional Mill, Heap Leach, and ISR Facilities.

Is uranium used in bombs? ›

Plutonium-239 and uranium-235 are the most common isotopes used in nuclear weapons.

What does uranium do to the body? ›

Main uranium health effects

Uranium's main target is the kidneys. Kidney damage has been seen in humans and animals after inhaling or ingesting uranium compounds. However, kidney damage has not been consistently found in soldiers who have had uranium metal fragments in their bodies for several years.

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